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2011, 05, v.33;No.130 46-48+101
石墨烯修饰电极对肾上腺素电催化性能的研究
基金项目(Foundation): 山东省自然科学基金资助项目(ZR2009BM003)
邮箱(Email):
DOI: 10.16393/j.cnki.37-1436/z.2011.05.008
摘要:

制备了石墨烯修饰电极,研究了肾上腺素在修饰电极上的电化学行为.实验结果表明,石墨烯修饰电极对肾上腺素有明显的催化作用.在pH=5的柠檬酸-磷酸氢二钠的缓冲溶液中,肾上腺素的氧化峰电流与浓度在2.0×10-4~2.0×10-3 mol/L范围内呈线性关系,检出限为2.0×10-6 mol/L.修饰电极表现出良好的稳定性.

Abstract:

Graphene modified glassy carbon electrode was prepared,and the electrochemical behaviors of epinephrine was studied on this modified electrode.Experimental results show that the graphene modified electrode has excellent catalytic properties for redox of epinephrine.In PBS(pH=5) solution,the oxidation peak current was linear with the concentration of EP in the range of 2.0×10-4 mol/L2.0 ×10-3mol/L.The detection limit is 2.0×10-6mol/L.The modified electrode showed good stability

参考文献

[1]Novoselov K S,Geim A K,Morozov S V,et al.Electric fieldeffect in atomically thin carbon films[J].Science 2004,306(5696):666-669.

[2]杨长玲,刘云芸,孙彦平.石墨烯的制备及电化学性能[J].电源技术,2010,34(9):177-180.

[3]Lin Y M,Jenkins K A,Carcia A V.Operation of graphenetransistors at cigahertz fequencies[J].Nano letters,2009,9(1):422-426.

[4]Wang Y,Li Y M,Tang L H,et al.Application of graphene-modified electrode for selective detection of dopamine[J].E-lectrochemistry Communications,2009,11:889-892.

[5]LiJ,GuoSJ,.ZhaiYM,et al.Nafion–graphene nanocompos-ite film as enhanced sensing platform forultrasensitive determi-nation of cadmium[J].Electrochemistry Communications,2009,11:1085–1088.

[6]欧陵斌.单壁碳纳米管修饰电极对去甲肾上腺素的电化学检测[J].中国实用医药,2010,5(3):5-7.

[7]薛启冥.神经系统的生理和病理化学[M].北京:科学出版社,1978:102.

[8]孙延一,吴康兵,胡胜水.多壁碳纳米管Nafion化学修饰电在高浓度抗坏血酸和尿酸体系中选择性测定多巴胺[J].高等学校化学学报,2002,23(11):2067-2069.

[9]Service R F.Carbon Sheets an Atom Thick Give Rise to Gra-phene Dreams[J].Science,2009,324:875-877.

基本信息:

DOI:10.16393/j.cnki.37-1436/z.2011.05.008

中图分类号:O646.54

引用信息:

[1]郭宪厚,李金金,同元辉,等.石墨烯修饰电极对肾上腺素电催化性能的研究[J].菏泽学院学报,2011,33(05):46-48+101.DOI:10.16393/j.cnki.37-1436/z.2011.05.008.

基金信息:

山东省自然科学基金资助项目(ZR2009BM003)

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