朱琪,吕惠萍

• 1:菏泽学院化学化工系

摘要(Abstract)：

羧酸类有机锡化合物的合成规律和结构特点,是目前此类化合物研究的热点问题之一.概述了一烃基锡羧酸酯、二烃基锡羧酸酯和三烃基锡羧酸酯合成及其结构的研究现况.

关键词(KeyWords)： 羧酸类;有机锡化合物;合成;结构

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 朱琪,吕惠萍

DOI: 10.16393/j.cnki.37-1436/z.2015.02.011

参考文献(References)：

• [1]Pearson R G.Hard and soft acids and bases[J].J.Am.Chem.Soc.,1963,85(22):3533-3539.
• [2]Bondi A.van der Waals volumes and radii[J].J.Phys.Chem.,1964,68(3):441-451.
• [3]Huheey J E,Keiter E A,Keiter R L.Inorganic Chemistry:Principles of Structure and Reactivity[M].4thed.New York:Harper Collins College Publishers,1993:292.
• [4]Holmes R R,Schmid C G,Chandrasekhar V,et al.Oxo carboxylate tin ladder cluster.A newstructural class of organotin compound[J].J.Am.Chem.Soc.,1987,109(5):1408-1414.
• [5]Alcock N W,Roe S M.Phenyltin trichloroacetate complexes:preparations and structures[J].J.Chem.Soc.Dalton Trans,1989:1589-1598.
• [6]Chandrasekhar V,Day R O,Holmes R R.A new structural form of tinoctahedrally coordinated in a drum-shaped molecule[J].Inorg.Chem.,1985,24(13):1970-1971.
• [7]Chandrasekhar V,Nagendran S,Bansal S,et al.An iron wheel on a tin drum:A novel assembly of ahexaferrocene unit on a tin-oxygen cluster[J].Angew.Chem.Int.Ed.Engl.,2000,39(10):1833-1835.
• [8]Day R O,Chandrasekhar V,Kumara Swamy K C,et al.Organotin clusters.3.Novel drums and mixed-drum organooxotin clusters from carboxylic,phosphinic,and phosphoric acids[J].Inorg.Chem.,1988,27(16):2887-2893.
• [9]Kumara Swamy K C,Nagabrahmanandachari S,Raghuraman K.A novel trinuclear n-butyltin cluster incorporating three ferrocene carboxylate substituents[J].J.Organomet.Chem.,1999,587(1):132-135.
• [10]Gielen M,El Khloufi A,Biesemans M,et al.(2-Methylthio-3-Pyridinecarboxylato)-diethyltin and di-nbutyltin compounds:synthesis,spectroscopic characterization and in vitro antitumour activity.X-ray crystal structure of bis[diethyl(2-methylthio-3-Pyridinecarboxylato)tin]oxide and of diethyltin bis(2-methylthio-3-pyridinecarboxylate)[J].Polyhedron,1992,11(15):1861-1868.
• [11]Teoh S G,Ang S H,Looi E S,et al.Synthesis and crystal structure of Di-n-butylbis(2-amino-5-chlorobenzoato)tin(IV)[J].J.Organomet.Chem.,1996,523(1):75-78.
• [12]García-Zarracino R,Ramos-Quiňones J,Hpfl H.Self-Assembly of Dialkyltin(IV)Moieties and Aromatic Dicarboxylates to Complexes with a Polymeric or a Discrete Trinuclear Macrocyclic Structure in the Solid State and a Mixture of Fast Interchanging Cyclooligomeric Structures in Solution[J].Inorg.Chem.,2003,42(12):3835-3845.