二异丙基二硫代氨基甲酸与二氯化钯的配合物的合成、结构和表征Crystal Structure and Characterization of Pd(II)Bis(diisopropyldithiocarbamate) Complex
刘春华,李雪梅,张书圣
摘要(Abstract)：
通过X—射线晶体衍射,确定了化合物[Pd(iPr_2dtc)_2]的晶体和分子结构。晶体属单斜晶系,空间群为:P2(1)/C,晶胞参数分别为:a=0.81664(1),b=1.81265(2),c=1.48699(2)nm,α=90,β=101.667(1),γ=90°,Z=2。钯(Ⅱ)正离子作为中心对称离子呈现平面正方形的几何构型,二异丙基二硫代氨基甲酸根阴离子作为二齿配体通过二个S原子与钯(Ⅱ)原子配位。分子间形成的C—H…S氢键使配合物趋于稳定。
关键词(KeyWords)： 钯配合物;二异丙基二硫代氨基甲酸配体;平面正方形结构;氢键
基金项目(Foundation):
作者(Author): 刘春华,李雪梅,张书圣
DOI: 10.16393/j.cnki.37-1436/z.2002.04.010
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