基于铝离子敏化牡丹提取物(丹皮酚)荧光法定量分析Al3+的研究Quantitative Analysis of Al3+ Using a Fluorescence Method Based on Aluminum Ion-Sensitized Peony Extract (Paeonol)
刘海生,崔开瑞,陈长坤,吴红松
摘要(Abstract):
饮用水是人体铝元素的主要摄入来源.微量铝离子可对人体健康造成很大危害.WHO(世界卫生组织)规定,饮用水中允许的最高铝离子浓度为200μg/L(7.41μmol/L).因此铝离子的高灵敏检测显得尤为重要.目前常用的铝离子检测方法存在操作麻烦,周期长等缺点,所以构建一种简便、快捷的铝离子检测方法尤为重要.丹皮酚是一种提取自牡丹皮的有机化合物,其与Al~(3+)结合后荧光会数倍增强.基于丹皮酚与铝离子结合产生荧光增强现象,建立了一种检测铝离子的荧光分析方法.此方法只需常温反应5 min,并且检测限为0.5μmol/L(线性范围:0~100μmol/L),构建的检测方法具有快速、低成本、简单、高特异性和高灵敏等优点,有很好的应用前景.
关键词(KeyWords): 荧光增敏法;丹皮酚;Al~(3+);低成本;快速检测
基金项目(Foundation): 国家自然科学基金(8200477);; 菏泽学院博士基金(XY22BS21)
作者(Author): 刘海生,崔开瑞,陈长坤,吴红松
DOI: 10.16393/j.cnki.37-1436/z.2024.02.016
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