邻甲苯胺在1,2-二氯乙烷中的电子转移性质及H2O2的影响Electron-Transfer Properties of o-Toluidine in 1,2-Dichloromethane and the Influences of Hydrogen Peroxide
陈琪,高俊侠,郁章玉
摘要(Abstract)：
以1,2-二氯乙烷为溶剂,利用循环伏安法研究了邻甲苯胺在铂电极上的电子转移性质,并测试了H2O2存在时邻甲苯胺的循环伏安特性,探讨了电极反应机理.结果表明,在低浓度的非质子溶剂中邻甲苯胺正离子主要发生“尾-尾”耦合,其电极反应机理为包含随后转化步骤的反应过程,即ECE历程.
关键词(KeyWords)： 邻甲苯胺;循环伏安;电子转移性质;过氧化氢
基金项目(Foundation): 山东省自然科学基金资助项目(Y2000B03);; 山东省教育厅科技计划重点项目(J04B11)
作者(Author): 陈琪,高俊侠,郁章玉
DOI: 10.16393/j.cnki.37-1436/z.2005.05.009
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