徐环环,李丹,陈荣,王学亮,郁章玉

• 1:曲阜师范大学化学与化工学院
• 2:菏泽学院化学与化工系

摘要(Abstract)：

儿茶酚胺是一种含有儿茶酚和胺基的神经类物质,包括去甲肾上腺素、肾上腺素和多巴胺.儿茶酚胺的分析测定在医学临床应用和生物学研究方面具有重要的意义.综述了近30年来化学修饰电极在儿茶酚胺物质的电化学测定中的应用,这种方法具有简便、快速、灵敏、准确的特点.

关键词(KeyWords)： 儿茶酚胺;电化学测定;修饰电极;应用

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金资助项目(21105023);; 山东省自然科学基金资助项目(ZR2009BM003)

作者(Author): 徐环环,李丹,陈荣,王学亮,郁章玉

DOI: 10.16393/j.cnki.37-1436/z.2013.02.008

参考文献(References)：

• [1]贾贞,刘淑芳,孙长侠,等.儿茶酚胺电化学分析法的研究进展[J].德州学院报,2008,20(4):52-55.
• [2]Li Y,Umasankar Y,Chen SH M.Multiwalled carbon nano-tubes with poly(NDGAChi)biocomposite film for the elec-trocatalysis of epinephrine and norepinephrine[J].Anal.Biochem.,2009,388:288-295.
• [3]Beitollahi H,Ardakani M M,Ganjipour B,et al.Novel2,2'-[1,2-ethanediylbis(nitriloethylidyne)]-bis-hydro-quinone double-wall carbon nanotube paste electrode forsimultaneous determination of epinephrine,uric acid and fo-lic acid[J].Biosensors and Bioelectronics,2008,24:362-368.
• [4]Kim Y R,Bong S,Kang Y J,et al.Electrochemical detec-tion of dopamine in the presence of ascorbic acid using gra-phene modified electrodes[J].Biosensors and Bioelectron-ics,2010,25:2366-2369.
• [5]郭宪厚,李金金,同元辉,等.石墨烯修饰电极对肾上腺素电催化性能的研究[J].菏泽学院学报,2011,33(5):46.
• [6]同元辉,郭宪厚,焦翠玲,等.羧基化石墨烯修饰玻碳电极对多巴胺电催化性能影响的研究[J].菏泽学院学报,2012,34(2):56-59.
• [7]Thiagarajan S,Yang R F,Chen SH M.Palladium nanopar-ticles modified electrode for the selective detection of cate-cholamine neurotransmitters in presence of ascorbic acid[J].Bioelectrochemistry,2009,75:163-169.
• [8]uczak T.Comparison of electrochemical oxidation of epi-nephrine in the presence of interfering ascorbic and uricacids on gold electrodes modified with S-functionalizedcompounds and gold nanoparticles[J].Electrochemica Ac-ta,2009,54:5893-5870.
• [9]方宾,张伟,卫寿平,等.磁场作用下制备CNTs/Fe3O4修饰电极及电催化测定多巴胺[J].池州学院学报,2007,21(5):51-53.
• [10]Zheng M,Zhou Y,Chen Y,et al.Electrochemical behav-ior of dopamine in the presence of phosphonate and the de-termination of dopamine at phosphonate modified zirconiafilms electrode with highly antifouling capability[J].Elec-trochemica Acta 2010,55:4789-4798.
• [11]Tsai T H,Thiagarajan S,Chen SH M,et al.Ionic liquidassisted synthesis of nano Pd–Au particles and applica-tion for the detection of epinephrine,dopamine and uricacid[J].Thin Solid Films,2012,520:3054-3059.
• [12]Chernyshov D V,Shvedene N V,Antipova E R,et al.I-onic liquid-based miniature electrochemical sensors forthe voltammetric determination of catecholamines[J].An-alytica Chimica Acta,2008,621:178-184.
• [13]董绍俊,车广礼,谢远武.化学修饰电极[M].北京:科学出版社,2003.
• [14]Zhang L,Sun Y G,Lin X Q.Separation of anodic peaksof ascorbic acid and dopamine at an a-alanine covalentlymodified glassy carbon electrode[J].Analyst,2001,126:1760-1763.
• [15]Wang L,Huang P F,Wang H J,et al.Covalent modifica-tion of glassy carbon electrode with aspartic acid for simul-taneous determination of hydroquinone and catechol[J].Annali di Chimica,2007,97:395-404.
• [16]Yu ZH Y,Li X CH,Wang X L,et al.Voltammetric de-termination of dopamine and norepinphrine on a lassy car-bon electrode modified with poly(L-aspartic acid)[J].J.Chem.Sci.,2012,124(2):537-544.
• [17]Yu Z Y,Li X Ch,Wang X L,et al.Studies on the elec-trochemical behaviors of epinephrine at a Poly(l-asparticacid)modified glassy carbon electrode and its analyticalapplication[J].Int.J.Electrochem.Sci.,2011,6:3890–3901.
• [18]费俊杰,谭红艳,陈小明,等.锇联吡啶氧化还原聚合物膜修饰电极对肾上腺素的电催化氧化及安培检测[J].催化学报,2006,27(7):619-623.
• [19]何星存,李平,莫金恒.聚2,6-吡啶二甲酸膜对儿茶酚和对苯二酚电氧化的催化性能及其应用[J].化学研究与应用,2000,12(2):152-155.
• [20]孙登明,陈宁生,冷艳芳.聚甲基蓝修饰电极的制备及对多巴胺的测定[J].分析实验室,2004,23(5):41-43.
• [21]Atta N F,EI-Kady M F,Galal A.Palladium nanoclus-ters-coated polyfuran as a novel sensor for catecholamineneurotransmitters and paracetamol[J].Sensors and Actua-tors B,2009,141:566-574.
• [22]梁瑞,赫春香.聚苯胺修饰电极对多巴胺、尿酸、抗坏血酸的电化学区分效应[J].高师理科学刊,2011,31(1):69-72.
• [23]Wang J X,Li M X,Shi Z J,et al.Electrocatalytic Oxida-tion of Norepinephrine at a Glassy Carbon Electrode Modi-fied with Single Wall Carbon Nanotubes[J].Electroanaly-sis,2002,14:225-230.
• [24]Zheng M,Zhou Y,Chen Y,et al.Electrochemical behav-ior of dopamine in the presence of phosphonate and the de-termination of dopamine at phosphonate modified zirconiafilms electrode with highly antifouling capability[J].Elec-trochimica Acta,2010,55:4789-4798.
• [25]Martínez-Huitle C A,Cerro-Lopez M,Quiroz M A.Electrochemical Behaviour of Dopamine at Covalent Modi-fied Glassy Carbon Electrode with L-Cysteine:Prelimina-ry Results[J].Materials Research,2009,12,375-384.
• [26]Bouhouti H E,Naranjio-Rodríguez I,Hidalgo-de Cis-neros J L,et al.Electrochemical behaviour of epinephrineand uric acid at a Sonogel–Carbon L-Cysteine modifiedelectrode[J].Talanta,2009,79:22-26.
• [27]Bian C L,Zeng Q X,Xiong H Y,et al.Electrochemistryof norepinephrine on carbon-coated nickel magnetic nano-particles modified electrode and analytical applications[J].Bioelectrochemistry,2010,79:1-5.
• [28]Mazloum-Ardakani M,Beitollahi H,Sheikh-Mohseni MA,et al.Novel nanostructure electrochemical sensor forelectrocatalytic determination of norepinephrine in the pres-ence of high concentrations of acetaminophene and folicacid[J].Applied Catalysis A:General,2010,378:195-201.
• [29]Santos D P,Zanoni M V B,Bergamini M F,et al.Poly(glutamic acid)nanofibre modified glassy carbon elec-trode:Characterization by atomic force microscopy,volta-mmetry and electrochemical impedance[J].Electrochimi-ca Acta,2008,53:3991-4000.
• [30]Huang S H,Liao H H,Chen D H.Simultaneous determi-nation of norepinephrine,uric acid,and ascorbic acid at ascreen printed carbon electrode modified with polyacrylicacid-coated multi-wall carbon nanotubes[J].Biosen-sors and Bioelectronics,2010,25:2351-2355.
• [31]Ensafi A A,Taei M,Khayaymian T,et al.Highly selec-tive determination of ascorbic acid,dopamine,and uricacid by differential pulse voltammetry using poly(sulfonazoIII)modified glassy carbon electrode[J].Sensors and Ac-tuators B,2010,147:213-221.
• [32]Chen Q P,Ai SH Y,Ma Q,et al.Selective determinationof dopamine in the presence of ascorbic acid using ferroce-nyl-tethered PAMAM dendrimers modified glassy carbonelectrode[J].J.Appl.Electrochem.,2010,40:1379-1385.
• [33]Zhou X,Zheng N,Hou SH R,et al.Selective determina-tion of dopamine in the presence of ascorbic acid at a multi-wall carbon nanotube-poly(3,5-dihydroxy benzoicacid)film modified electrode[J].Journal of Electroanalyt-ical Chemistry,2010,642:30-34.
• [34]Goyal R N,Agrawal B.Ag ion irradiated based sensor forthe electrochemical determination of epinephrine and 5-hydroxytryptamine in human biological fluids[J].Analyti-ca Chimica Acta,2012,743:33-40.
• [35]Tsai T H,Thiagarajan S,Chen SH M,et al.Ionic liquidassisted synthesis of nano Pd-Au particles and applicationfor the detection of epinephrine,dopamine and uric acid[J].Thin Solid Films,2012,520:3054-3059.
• [36]Liu X J,Ye D X,Luo L Q,et al.Highly sensitive deter-mination of epinephrine by a MnO2/Nafion modified glassycarbon electrode[J].Journal of Electroanalytical Chemis-try,2012,665:1-5.
• [37]Huo J E,Li J,Li Q M.Study on electrochemical behav-iors and the reaction mechanisms of dopamine and epineph-rine at the pre-anodized inlaying ultrathin carbon paste e-lectrode with nichrome as a substrate[J].Materials Sci-ence and Engineering C,2013,33:507-511.
• [38]Cui F,Zhang X L.Electrochemical sensor for epinephrinebased on a glassy carbon electrode modified with graphene/gold nanocomposites[J].Journal of ElectroanalyticalChemistry,2012,669:35-41.