碳锡复合材料在锂离子电池负极中的应用Application of Carbon- tin Composite Material in Anode of Lithium Ion Battery
刘庆华
摘要(Abstract):
碳材料是目前广泛采用的负极材料,但是低电化学容量一直制约着锂离子电池的发展.锡基材料由于高电化学容量,是一种有巨大发展潜力的锂离子电池负极材料,但仍存在充放电过程中循环寿命差、材料体积变化大、易粉化等问题.因此,需要寻找一种可以结合两种材料优势的方法.简要介绍了碳基、锡基材料的发展现状及存在的问题,并简述了碳锡复合材料的研发方向及前景.
关键词(KeyWords): 锂离子电池;负极材料;碳锡复合材料
基金项目(Foundation):
作者(Author): 刘庆华
DOI: 10.16393/j.cnki.37-1436/z.2015.02.012
参考文献(References):
- [1]Tarascon J M,Armand M.Issues and challenges facing rechargeable lithium batteries[J].Nature,2001,414:359-367.
- [2]杨宁,熊大民,王剑华.锂离子电池负极材料的研究进展[J].电工材料,2004(3):32-34.Yang N,Xiong D M,Wang J H.The Progress in Research on Anode Materials for Lithium_Ion Batteries[J].Electrical Engineering Materials,2004(3):32-34.
- [3]Yang J,Ruifen Z,Zhaolin L.Dispersion of Sn and Sn O on carbon anodes[J].J Power Sources,2000,90(1):70-75.
- [4]林克芝,王晓琳,徐艳辉.锂离子电池锡基负极材料的改性研究进展[J].电源技术,2005,29(1):62-65.Lin K Z,Wang X L,Xu Y X.Recent Development of Tin-Based Materidals as Anode of the Lithium Ion Battery[J].Chinese Journal of Power Sources,2005,29(1):62-65.
- [5]Choi W,Lee J Y,Jung B H,et al.Microstructure and electrochemical properties of a nanometer-scale tin anode for lithium secondary batteries[J].Journal of Power Sources,2004,136(1):154-159.
- [6]Limthongkul P,Wang H,Chiang Y.Nanocomposite Liion battery anodes produced by the partial reduction of mixed oxides[J].Chem Mater,2001,13:2397-2402.
- [7]Tirado J L.Inorganic materials for the negative electrode of lithium-ion batteries:state-of-the-art and future prospects[J].Materials Science and Engineering R,2003,40(3):103-136.
- [8]Yang J,Wachtler M,Winter M,et al.Sub-microcrystalline Sn and Sn-Sn Sb powders as lithium storage materials for lithium-ion batteries[J].Electrochemical and SolidState Letters,1999,2(4):161-163.
- [9]Guo Z P,Zhao Z W,Liu H K,et al.Electrochemical lithiation and de-lithiation of MWNT–Sn/Sn Ni nanocomposites[J].Carbon,2005,43(7):1392-1399.
- [10]Wen Z H,Wang Q,Zhang Q,et al.In situ growth of mesoporous Sn O2on multiwalled carbon nanotubes:a novel composite with porous-tube structure as anode for lithium batteries[J].Advanced Functional Materials,2007,17(15):2772-2778.
- [11]Wang Y,Wu M,Zheng Jiao.Sn@CNT and Sn@C@CNT nanostructures for superior reversible lithium ion storage[J].Chemistry of Materials,2009,21(14):3210-3215.
- [12]Park M S,Needham S A,Wang G X,et al.Nanostructured Sn Sb/carbon nanotube composites synthesized by reductive precipitation for lithium-ion batteries[J].Chemistry of Materials,2007,19(10):2406-2410.
- [13]魏巍,王久林,杨军,等.锂离子电池锡基负极材料的研究进展[J].化工进展,2010,29(1):80-87.
- [14]Noh M,Kwon Y,Lee H,et al.Amorphous carbon-coated tin anode material for lithium secondary battery[J].Chem Mater,2005,17:1926-1929.
- [15]Lee K T,Jung Y S,Oh S M.Synthesis of tin-encapsulated spherical hollow carbon for anode material in lithium secondary batteries[J].J Am Chem Soc,2003,125:5652-5653.
- [16]Lou X W,Li C M,Archer L A.Designed synthesis of coaxial Sn O2@carbon hollow nanospheres for highly reversible lithium storage[J].Advanced Materials,2009,21(24):2536-2539.
- [17]Wang Y,Su F,Lee J Y,et al.Crystalline carbon hollow spheres,crystalline carbon-Sn O2hollow spheres,and crystalline Sn O2hollow spheres:synthesis and performance in reversible Li-ion storage[J].Chemistry of Materials,2006,18(5):1347-1253.
- [18]Zhang W M,Hu J S,Guo Y G,et al.Tin-nanoparticles encapsulated elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries[J].Adv.Mater.,2008,20(6):1160-1165.
- [19]Lonyuk B,Apachitei I,Duszczyk J.The effect of oxide coatings on fatigue properties of 7475-T6 aluminum alloy[J].Surf Coat Techn,2007,201(21):8688-8694.
- [20]Derrien G,Hassoun J,Panero S,et al.Nanostructured Sn–C Composite as an Advanced Anode Material in High-Performance Lithium-Ion Batteries[J].Advanced Materials,2007,19(17):2336-2340.
- [21]Noh M,Kwon Y,Lee H,et al.Amorphous carbon-coated tin anode material for lithium secondary battery[J].Chem Mater,2005,17(8):1926–1929.
- [22]Suzuki T,Hasegawa T,Mukai S R,et al.A theoretical study on storage states of Li ions in carbon anodes of Li ion batteries using molecular orbital calculations[J].Carbon,2003,41(10):1933-1939.
- [23]Paek S M,Yoo E,Honma I.Enhanced cyclic performance and lithium storage capacity of Sn O2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure[J].Nano Lett,2009,9(1):72-75.
- [24]Wang X Y,Zhou X F,Yao K,et al.A Sn O2/graphene composite as a high stability electrode for lithium ion batteries[J].Carbon,2011,49(1):133-139.
- [25]Li Y M,Lv X J,Lu J,et al.Preparation of Sn O2-nanocrystal/graphene-nanosheets composites and their lithium storage ability[J].J.Phys.Chem.C,2010,114(49):21770-21774.